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- W2058442598 abstract "Crystals of [Fe3(CO)9(PMe2Ph)3] are orthorhombic, space group Pbca, with a= 16·76, b= 18·75, c= 23·43 Å, Z= 8. The structure was refined by least-squares with isotropic temperature factors to a final R of 11·4% for 1394 independent reflections. The molecule retains the skeleton of Fe3(CO)12, the isosceles triangle of iron atoms having its shortest (2·540 Å) side bridged by two carbonyl groups whilst the two longer (2·688 Å) sides are unbridged. The three phosphine molecules, one attached to each iron atom, occupy co-ordination positions which place all three phosphorus atoms coplanar with the triangle of iron atoms." @default.
- W2058442598 created "2016-06-24" @default.
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- W2058442598 date "1971-01-01" @default.
- W2058442598 modified "2023-09-26" @default.
- W2058442598 title "Crystal structure of di-µ-carbonyl-heptacarbonyltris[(dimethyl)phenylphosphine]-triangulo-tri-iron, [Fe3(CO)9(PMe2Ph)3]" @default.
- W2058442598 doi "https://doi.org/10.1039/j19710003430" @default.
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