Matches in SemOpenAlex for { <https://semopenalex.org/work/W2058463417> ?p ?o ?g. }
- W2058463417 endingPage "11504" @default.
- W2058463417 startingPage "11497" @default.
- W2058463417 abstract "Intramolecular charge separation (CS) and charge recombination (CR) processes of the dyad molecule linking C60 and N,N-di(6-tert-butylbiphenyl)benzenamine (BBA) were investigated by pico- and nanosecond laser flash photolysis methods. Furthermore, intermolecular electron transfer to a methanofullerene (C61H2) was also investigated; the electron-transfer rate between triplet excited C61H2 and BBA was somewhat slower than that of C60 due to less negative reduction potential of C61H2. As for the BBA−C60 dyad molecule, CS was successfully observed in polar solvents by excitation of C60 moiety with picosecond laser pulse, while only the intersystem crossing was observed in nonpolar solvent. The CS process in the Marcus “normal region” was confirmed. In moderately polar solvent, radical ion pairs recombined within a few nanoseconds to generate the ground state and the triplet excited state of the C60-moiety. On the other hand, in polar solvents, the radical ion pairs decayed by two-steps: Most part decayed within 1 ns, while the radical ions were also observed in the submicrosecond region for a ca. 10% yield of generated BBA•+-C60•-. An equilibrium between CS and triplet states was proposed for the mechanism of long-lived CS state." @default.
- W2058463417 created "2016-06-24" @default.
- W2058463417 creator A5000806412 @default.
- W2058463417 creator A5005400068 @default.
- W2058463417 creator A5015658424 @default.
- W2058463417 creator A5019812735 @default.
- W2058463417 creator A5041224702 @default.
- W2058463417 creator A5080787029 @default.
- W2058463417 date "2000-11-17" @default.
- W2058463417 modified "2023-09-26" @default.
- W2058463417 title "Photoinduced Charge Separation and Recombination in a Novel Methanofullerene−Triarylamine Dyad Molecule" @default.
- W2058463417 cites W1530818404 @default.
- W2058463417 cites W1971183713 @default.
- W2058463417 cites W1972815509 @default.
- W2058463417 cites W1987415128 @default.
- W2058463417 cites W1992275488 @default.
- W2058463417 cites W1996128923 @default.
- W2058463417 cites W1997211506 @default.
- W2058463417 cites W2001270915 @default.
- W2058463417 cites W2009240902 @default.
- W2058463417 cites W2020039988 @default.
- W2058463417 cites W2025671500 @default.
- W2058463417 cites W2029695907 @default.
- W2058463417 cites W2029697721 @default.
- W2058463417 cites W2032945857 @default.
- W2058463417 cites W2034311513 @default.
- W2058463417 cites W2038012332 @default.
- W2058463417 cites W2039809872 @default.
- W2058463417 cites W2048707809 @default.
- W2058463417 cites W2049700734 @default.
- W2058463417 cites W2050954402 @default.
- W2058463417 cites W2057474568 @default.
- W2058463417 cites W2059836006 @default.
- W2058463417 cites W2062327380 @default.
- W2058463417 cites W2068342391 @default.
- W2058463417 cites W2069506896 @default.
- W2058463417 cites W2069668564 @default.
- W2058463417 cites W2076558433 @default.
- W2058463417 cites W2078874694 @default.
- W2058463417 cites W2081097296 @default.
- W2058463417 cites W2084544815 @default.
- W2058463417 cites W2091933586 @default.
- W2058463417 cites W2096174364 @default.
- W2058463417 cites W2100350057 @default.
- W2058463417 cites W2108004028 @default.
- W2058463417 cites W2123903421 @default.
- W2058463417 cites W2124295208 @default.
- W2058463417 cites W2134647722 @default.
- W2058463417 cites W2138422931 @default.
- W2058463417 cites W2144541387 @default.
- W2058463417 cites W2144823337 @default.
- W2058463417 cites W2145773666 @default.
- W2058463417 cites W2157962188 @default.
- W2058463417 cites W2169205842 @default.
- W2058463417 cites W2330290939 @default.
- W2058463417 cites W2949099349 @default.
- W2058463417 cites W2950257340 @default.
- W2058463417 cites W2950475723 @default.
- W2058463417 doi "https://doi.org/10.1021/jp002319b" @default.
- W2058463417 hasPublicationYear "2000" @default.
- W2058463417 type Work @default.
- W2058463417 sameAs 2058463417 @default.
- W2058463417 citedByCount "101" @default.
- W2058463417 countsByYear W20584634172012 @default.
- W2058463417 countsByYear W20584634172013 @default.
- W2058463417 countsByYear W20584634172014 @default.
- W2058463417 countsByYear W20584634172015 @default.
- W2058463417 countsByYear W20584634172016 @default.
- W2058463417 countsByYear W20584634172017 @default.
- W2058463417 countsByYear W20584634172018 @default.
- W2058463417 countsByYear W20584634172020 @default.
- W2058463417 countsByYear W20584634172021 @default.
- W2058463417 crossrefType "journal-article" @default.
- W2058463417 hasAuthorship W2058463417A5000806412 @default.
- W2058463417 hasAuthorship W2058463417A5005400068 @default.
- W2058463417 hasAuthorship W2058463417A5015658424 @default.
- W2058463417 hasAuthorship W2058463417A5019812735 @default.
- W2058463417 hasAuthorship W2058463417A5041224702 @default.
- W2058463417 hasAuthorship W2058463417A5080787029 @default.
- W2058463417 hasConcept C120665830 @default.
- W2058463417 hasConcept C121332964 @default.
- W2058463417 hasConcept C123669783 @default.
- W2058463417 hasConcept C145148216 @default.
- W2058463417 hasConcept C161790260 @default.
- W2058463417 hasConcept C166950319 @default.
- W2058463417 hasConcept C178790620 @default.
- W2058463417 hasConcept C181500209 @default.
- W2058463417 hasConcept C184779094 @default.
- W2058463417 hasConcept C185592680 @default.
- W2058463417 hasConcept C2776568683 @default.
- W2058463417 hasConcept C2780497573 @default.
- W2058463417 hasConcept C2781018080 @default.
- W2058463417 hasConcept C32909587 @default.
- W2058463417 hasConcept C33062035 @default.
- W2058463417 hasConcept C520434653 @default.
- W2058463417 hasConcept C55005982 @default.
- W2058463417 hasConcept C55493867 @default.
- W2058463417 hasConcept C65165184 @default.