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- W2058472925 abstract "Abstract The structure and the phase transitions of the 1st stage organo-alkali graphitide are mainly determined by the interactions between the three components: alkali ion, organic molecule and graphene layer. By changing the nature of the molecule, the relative intensities of these forces are modified. Using non polar molecules, the alkali-graphitic plane interaction is predominant, limiting the thickness of the intercalated layer and only order-disorder transitions of this layer are observed. When polar molecules-like THF are intercalated, the molecule-alkali interaction is increased and the parameter of the final compound is mainly determined by the structure of “complexes” which are formed in the intercalated layer. However, the graphene layer can also influence the organisation of the compound by modifying the structure of these complexes (with the molecule-graphene plane interaction) or by their elastic properties which decorrelate the plane at low temperature in Cs(THF)1.7C24. Various phase transitions are then observed as a function of the temperature." @default.
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- W2058472925 date "1991-04-01" @default.
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- W2058472925 title "The origin of some phase transitions observed in the organo-alkali graphite intercalation compounds" @default.
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- W2058472925 doi "https://doi.org/10.1080/01411599108207967" @default.
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