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- W2058475419 abstract "Abstract This work reports on the synthesis, characterization, photophysical properties and electrochemical characterization of new tetra-substituted titanium phthalocyanine with dimethylaminoethanol groups on peripheral positions ( 2 ) and water-soluble quaternized counterpart. The water-soluble titanium(IV) phthalocyanine derivative ( 3 ) was found to be aggregated in aqueous media but was partially or fully disaggregated in the presence of a surfactant Triton X-100. The capping of the titanyl (metaloxo) inner core with catechol derivatives ( 4 – 7 ) were also synthesized. The axially substituted titanium phthalocyanines show high solubility and a low aggregation tendency due to the steric hindrance. The structures of these compounds were characterized by using elemental analyses, UV–Vis, FT-IR, 1 H NMR and mass spectroscopies. Their photophysical properties were also studied and fluorescence quantum yields were found to range from 0.02 to 0.13. The electrochemical properties of 2 were also investigated by using cyclic voltammetry in this report." @default.
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- W2058475419 date "2013-05-01" @default.
- W2058475419 modified "2023-10-17" @default.
- W2058475419 title "Synthesis, electrochemical and photophysical studies of axially substituted quarternizable titanyl phthalocyanines" @default.
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- W2058475419 doi "https://doi.org/10.1016/j.dyepig.2012.12.022" @default.
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