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- W2058484788 abstract "The relative rates of addition of difluorocarbene to a series of methyl-substituted olefins have been determined and correlated with similar data for dichlorocarbene, chlorofluorocarbene and ground-state oxygen atoms. The electrophilic nature and stabilization of difluorocarbene by the fluorine substituents is discussed. Relative activation energies for the difluorocyclopropane-forming reaction have been estimated and correlated with properties of the olefins as derived from molecular orbital theory." @default.
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- W2058484788 date "1969-09-01" @default.
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- W2058484788 title "Reactivities in olefin-difluorocarbene reactions" @default.
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- W2058484788 doi "https://doi.org/10.1002/kin.550010503" @default.
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