FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2058487220> ?p ?o ?g. }

• W2058487220 abstract "Abstract The reactions Cl + SiHCl3 and Cl + SiH2Cl2 have been investigated with UV photoelectron spectroscopy and bands associated with the primary reaction products SiCl3 and SiHCl2 have been observed. The first vertical ionization energies of SiCl3 and SiHCl2 have been measured as (9.24 ± 0.03) and (9.06 ± 0.02) eV respectively. The corresponding band onsets are (8.45 ± 0.05) and (8.40 ± 0.05) eV. Evidence is presented, based on the results of ab initio molecular orbital calculations at the 6–31G**/MP2 level, that the experimental band onsets are upper limits of the adiabatic ionization energies. For each radical, by comparing the computed vertical ionization energy with the measured value, the calculated adiabatic ionization energy has been corrected to yield an estimate of the experimental adiabatic ionization energy. Using this procedure, the adiabatic ionization energies of SiCl3 and SiHCl2 are evaluated as (8.05 ± 0.10) and (7.90 ± 0.10) eV respectively. HCl and SiCl4 are found to be stable products of the Cl + SiHCl3 reaction, and HCl, SiCl2 and SiCl4 are products of the Cl + SiH2Cl2 reaction sequence. Similar studies have been made for the F + SiH2Cl2 and F + SiHCl3 reactions. F + SiH2Cl2 is notable in that it produces SiF2, SiFCl, and SiCl2 as secondary reaction products. The assignment of a reaction product band at (10.57 ± 0.01) eV vertical ionization energy to SiFCl has been supported by the results of ab initio molecular orbital calculations. For each reaction, spectra recorded at different reaction times allow a reaction scheme to be proposed." @default.
• W2058487220 created "2016-06-24" @default.
• W2058487220 creator A5001581344 @default.
• W2058487220 creator A5014356457 @default.
• W2058487220 creator A5028449676 @default.
• W2058487220 creator A5081457570 @default.
• W2058487220 date "1993-12-01" @default.
• W2058487220 modified "2023-09-26" @default.
• W2058487220 title "A study of the reactions of chlorine and fluorine atoms with SiH2Cl2 and SiHCl3, with ultraviolet photoelectron spectroscopy" @default.
• W2058487220 cites W1965339983 @default.
• W2058487220 cites W1970564566 @default.
• W2058487220 cites W1977404712 @default.
• W2058487220 cites W1982641736 @default.
• W2058487220 cites W1985879579 @default.
• W2058487220 cites W1988604590 @default.
• W2058487220 cites W1994385101 @default.
• W2058487220 cites W1999836725 @default.
• W2058487220 cites W2000929520 @default.
• W2058487220 cites W2001432909 @default.
• W2058487220 cites W2007930976 @default.
• W2058487220 cites W2015385724 @default.
• W2058487220 cites W2017345541 @default.
• W2058487220 cites W2018179294 @default.
• W2058487220 cites W2033990154 @default.
• W2058487220 cites W2040674611 @default.
• W2058487220 cites W2045673255 @default.
• W2058487220 cites W2051011344 @default.
• W2058487220 cites W2055181742 @default.
• W2058487220 cites W2058058759 @default.
• W2058487220 cites W2059797075 @default.
• W2058487220 cites W2066031954 @default.
• W2058487220 cites W2068104936 @default.
• W2058487220 cites W2074548393 @default.
• W2058487220 cites W2091493055 @default.
• W2058487220 cites W2098701827 @default.
• W2058487220 cites W2124866094 @default.
• W2058487220 cites W2149386115 @default.
• W2058487220 cites W285629475 @default.
• W2058487220 cites W2952764481 @default.
• W2058487220 cites W2953224793 @default.
• W2058487220 cites W2993306083 @default.
• W2058487220 doi "https://doi.org/10.1016/0368-2048(93)01836-4" @default.
• W2058487220 hasPublicationYear "1993" @default.
• W2058487220 type Work @default.
• W2058487220 sameAs 2058487220 @default.
• W2058487220 citedByCount "6" @default.
• W2058487220 countsByYear W20584872202012 @default.
• W2058487220 countsByYear W20584872202023 @default.
• W2058487220 crossrefType "journal-article" @default.
• W2058487220 hasAuthorship W2058487220A5001581344 @default.
• W2058487220 hasAuthorship W2058487220A5014356457 @default.
• W2058487220 hasAuthorship W2058487220A5028449676 @default.
• W2058487220 hasAuthorship W2058487220A5081457570 @default.
• W2058487220 hasConcept C109663097 @default.
• W2058487220 hasConcept C113196181 @default.
• W2058487220 hasConcept C121332964 @default.
• W2058487220 hasConcept C139358910 @default.
• W2058487220 hasConcept C145148216 @default.
• W2058487220 hasConcept C147192597 @default.
• W2058487220 hasConcept C147597530 @default.
• W2058487220 hasConcept C147789679 @default.
• W2058487220 hasConcept C175708663 @default.
• W2058487220 hasConcept C178790620 @default.
• W2058487220 hasConcept C184779094 @default.
• W2058487220 hasConcept C185592680 @default.
• W2058487220 hasConcept C198291218 @default.
• W2058487220 hasConcept C2781442258 @default.
• W2058487220 hasConcept C29563950 @default.
• W2058487220 hasConcept C32909587 @default.
• W2058487220 hasConcept C46141821 @default.
• W2058487220 hasConcept C49133459 @default.
• W2058487220 hasConcept C505241676 @default.
• W2058487220 hasConcept C506198293 @default.
• W2058487220 hasConcept C86025842 @default.
• W2058487220 hasConcept C97355855 @default.
• W2058487220 hasConceptScore W2058487220C109663097 @default.
• W2058487220 hasConceptScore W2058487220C113196181 @default.
• W2058487220 hasConceptScore W2058487220C121332964 @default.
• W2058487220 hasConceptScore W2058487220C139358910 @default.
• W2058487220 hasConceptScore W2058487220C145148216 @default.
• W2058487220 hasConceptScore W2058487220C147192597 @default.
• W2058487220 hasConceptScore W2058487220C147597530 @default.
• W2058487220 hasConceptScore W2058487220C147789679 @default.
• W2058487220 hasConceptScore W2058487220C175708663 @default.
• W2058487220 hasConceptScore W2058487220C178790620 @default.
• W2058487220 hasConceptScore W2058487220C184779094 @default.
• W2058487220 hasConceptScore W2058487220C185592680 @default.
• W2058487220 hasConceptScore W2058487220C198291218 @default.
• W2058487220 hasConceptScore W2058487220C2781442258 @default.
• W2058487220 hasConceptScore W2058487220C29563950 @default.
• W2058487220 hasConceptScore W2058487220C32909587 @default.
• W2058487220 hasConceptScore W2058487220C46141821 @default.
• W2058487220 hasConceptScore W2058487220C49133459 @default.
• W2058487220 hasConceptScore W2058487220C505241676 @default.
• W2058487220 hasConceptScore W2058487220C506198293 @default.
• W2058487220 hasConceptScore W2058487220C86025842 @default.
• W2058487220 hasConceptScore W2058487220C97355855 @default.
• W2058487220 hasLocation W20584872201 @default.
• W2058487220 hasOpenAccess W2058487220 @default.
• W2058487220 hasPrimaryLocation W20584872201 @default.

• next