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- W2058492512 abstract "A stereocontrolled synthetic route to optically pure (−)-(S)-ipsenol (1), the pheromone of Pityokteines curvidens and various other bark-beetle species is described. Key step of the synthesis is an enantioselective aldol reaction using a chiral titanium–carbohydrate complex (Scheme 1). The carboxylate function of the optically pure β-hydroxy acid 5 thus obtained in mol quantities is then elaborated to the diene moiety by standard methodology (Scheme 2)." @default.
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- W2058492512 date "1990-03-14" @default.
- W2058492512 modified "2023-10-10" @default.
- W2058492512 title "A Facile Synthesis of Optically Pure (?)-(S)-Ipsenol Using a Chiral Titanium Complex" @default.
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- W2058492512 doi "https://doi.org/10.1002/hlca.19900730215" @default.
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