Matches in SemOpenAlex for { <https://semopenalex.org/work/W2058506818> ?p ?o ?g. }
- W2058506818 endingPage "137" @default.
- W2058506818 startingPage "71" @default.
- W2058506818 abstract "After a brief review of the theory of mechanisms and kinetics of catalytic reactions, we formulate a number of mechanisms for the hypothetical reaction A2 + 2B → 2AB and derive analytic expressions for rate of reaction, activation enthalpy, and reaction orders. After a discussion of a number of pitfalls in the analysis of measured kinetic data, we use the models with a range of realistic parameters to analyze degree of rate control, reaction orders, Arrhenius plots, the origin of volcano curves, and the origin compensation effects. Abrupt changes in slope in the Arrhenius plot are traditionally interpreted as the signature of a change in rate limiting step or the onset of diffusion phenomena. One of the main results of our analysis is that simple mechanisms with realistic parameters display such signatures without a change in rate limiting step and in the absence of transport phenomena. Finally, we extend our analysis to more complex reaction mechanisms by analysis of a number of important industrial reactions." @default.
- W2058506818 created "2016-06-24" @default.
- W2058506818 creator A5008614519 @default.
- W2058506818 creator A5047713239 @default.
- W2058506818 creator A5063756343 @default.
- W2058506818 creator A5086720312 @default.
- W2058506818 date "2004-11-01" @default.
- W2058506818 modified "2023-10-07" @default.
- W2058506818 title "Analysis of simple kinetic models in heterogeneous catalysis" @default.
- W2058506818 cites W106896337 @default.
- W2058506818 cites W1490489470 @default.
- W2058506818 cites W1495226571 @default.
- W2058506818 cites W1858802623 @default.
- W2058506818 cites W1963885029 @default.
- W2058506818 cites W1967926050 @default.
- W2058506818 cites W1968806693 @default.
- W2058506818 cites W1971589175 @default.
- W2058506818 cites W1974287879 @default.
- W2058506818 cites W1977956754 @default.
- W2058506818 cites W1979008448 @default.
- W2058506818 cites W1980358572 @default.
- W2058506818 cites W1981229918 @default.
- W2058506818 cites W1984561839 @default.
- W2058506818 cites W1984830746 @default.
- W2058506818 cites W1987129969 @default.
- W2058506818 cites W1988247871 @default.
- W2058506818 cites W1989039744 @default.
- W2058506818 cites W1989282685 @default.
- W2058506818 cites W1990569915 @default.
- W2058506818 cites W1990650056 @default.
- W2058506818 cites W1992229885 @default.
- W2058506818 cites W1993409922 @default.
- W2058506818 cites W1993631590 @default.
- W2058506818 cites W1995448204 @default.
- W2058506818 cites W1996030617 @default.
- W2058506818 cites W2001219343 @default.
- W2058506818 cites W2004921847 @default.
- W2058506818 cites W2006550653 @default.
- W2058506818 cites W2006754868 @default.
- W2058506818 cites W2006831847 @default.
- W2058506818 cites W2006923192 @default.
- W2058506818 cites W2011895070 @default.
- W2058506818 cites W2014227857 @default.
- W2058506818 cites W2014593488 @default.
- W2058506818 cites W2015344901 @default.
- W2058506818 cites W2019839491 @default.
- W2058506818 cites W2024651849 @default.
- W2058506818 cites W2024900356 @default.
- W2058506818 cites W2028778704 @default.
- W2058506818 cites W2030276460 @default.
- W2058506818 cites W2037079359 @default.
- W2058506818 cites W2039026054 @default.
- W2058506818 cites W2039305269 @default.
- W2058506818 cites W2039331138 @default.
- W2058506818 cites W2041773932 @default.
- W2058506818 cites W2045433205 @default.
- W2058506818 cites W2057013856 @default.
- W2058506818 cites W2061163063 @default.
- W2058506818 cites W2061198081 @default.
- W2058506818 cites W2066738777 @default.
- W2058506818 cites W2068154215 @default.
- W2058506818 cites W2068513970 @default.
- W2058506818 cites W2070239635 @default.
- W2058506818 cites W2076687856 @default.
- W2058506818 cites W2079912420 @default.
- W2058506818 cites W2085559995 @default.
- W2058506818 cites W2091358860 @default.
- W2058506818 cites W2093893710 @default.
- W2058506818 cites W2095243215 @default.
- W2058506818 cites W2112663587 @default.
- W2058506818 cites W2118230245 @default.
- W2058506818 cites W2124198152 @default.
- W2058506818 cites W2127141422 @default.
- W2058506818 cites W2154556263 @default.
- W2058506818 cites W2169396043 @default.
- W2058506818 cites W2169904128 @default.
- W2058506818 cites W2952326550 @default.
- W2058506818 cites W4211069880 @default.
- W2058506818 doi "https://doi.org/10.1016/j.progsurf.2004.09.001" @default.
- W2058506818 hasPublicationYear "2004" @default.
- W2058506818 type Work @default.
- W2058506818 sameAs 2058506818 @default.
- W2058506818 citedByCount "98" @default.
- W2058506818 countsByYear W20585068182012 @default.
- W2058506818 countsByYear W20585068182013 @default.
- W2058506818 countsByYear W20585068182014 @default.
- W2058506818 countsByYear W20585068182015 @default.
- W2058506818 countsByYear W20585068182016 @default.
- W2058506818 countsByYear W20585068182017 @default.
- W2058506818 countsByYear W20585068182018 @default.
- W2058506818 countsByYear W20585068182019 @default.
- W2058506818 countsByYear W20585068182020 @default.
- W2058506818 countsByYear W20585068182021 @default.
- W2058506818 countsByYear W20585068182022 @default.
- W2058506818 countsByYear W20585068182023 @default.
- W2058506818 crossrefType "journal-article" @default.
- W2058506818 hasAuthorship W2058506818A5008614519 @default.
- W2058506818 hasAuthorship W2058506818A5047713239 @default.