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- W2058520910 abstract "Novel N-heterocyclic carbene (NHC) architecture of 1,4-phenylene-bis{imidazo[1,5-a]pyridine-4 iumhexaflurophosphate}, [1(HPF6)2] has been synthesized in two steps from commercially available starting materials. The p-phylene bridged free annulated imidazolium salt has been synthesized and characterized both in solution and solid-state and has been used to synthesize silver(I) and mercury(II)-NHC complexes using the basic metal precursors. The [Ag2(1)2][PF6]2 (2) was synthesized using [1(HPF6)2] by Ag2O method in acceptable yield. The dinuclear Hg(II) complex [Hg2(1)2][PF6]4 (3) consisting of two biscarbene ligand has been synthesized from Hg(OAc)2 and [1(HPF6)2]. The helical nature of Hg(II)-NHC (3) has been established from solid state X-ray structure." @default.
- W2058520910 created "2016-06-24" @default.
- W2058520910 creator A5010979417 @default.
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- W2058520910 creator A5046312899 @default.
- W2058520910 creator A5068236661 @default.
- W2058520910 creator A5074817588 @default.
- W2058520910 date "2013-10-01" @default.
- W2058520910 modified "2023-10-16" @default.
- W2058520910 title "Helical metal cage of silver(I) and mercury(II)-N-heterocyclic carbene complexes of 1,4-phenylene-bis{imidazo[1,5-a]pyridine-4-iumhexaflurophosphate}" @default.
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- W2058520910 doi "https://doi.org/10.1016/j.molstruc.2013.06.061" @default.
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