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• W2058540152 abstract "Abstract Reaction of the trilithium phosphazenate [{(THF) 2 Li} 3 {(PhNH) 3 (PhN) 3 P 3 N 3 }] with one equivalent of trimethylaluminium yields the first mixed‐metal phosphazenate complex [{(THF) 2 Li} 3 Me 2 Al{(PhNH) 2 (PhN) 4 P 3 N 3 }]. X‐ray structure analysis showed that the Me 2 Al group is accommodated in an N(exo)−P−N(exo) chelation site of the phosphazenate ligand. Two lithium ions reside in N(ring)−P−N(exo) sites, while the third lithium ion interacts with the ligand solely via an N(ring) atom. NMR spectroscopic data obtained from THF solution indicate a fluxional behaviour of the lithium ions, which oscillate between mono‐ and bidentate coordination sites. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)" @default.
• W2058540152 created "2016-06-24" @default.
• W2058540152 creator A5009723860 @default.
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• W2058540152 date "2003-09-01" @default.
• W2058540152 modified "2023-09-30" @default.
• W2058540152 title "Synthesis and Structure of [{(THF)₂Li}₃Me₂Al{(PhNH)₂(PhN)₄P₃N₃}], the First Mixed‐Metal Phosphazenate Complex" @default.
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• W2058540152 doi "https://doi.org/10.1002/ejic.200300222" @default.
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