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• W2058545787 abstract "Solutions containing benzylviologen and the fluorescent oxo-d1 ion MoOBr4(CH3CN)− in acetonitrile slowly deposit crystals of the electron donor-acceptor complex (BV)[MoOBr4(H2O)]Br·CH3CN: C26H27Br5MoN3O2, triclinic, space group P1; a=11.349(1), b=16.1048(8), c=18.720(1) Å; α=71.961(5), β=76.375(7), γ=82.484(6)°; Z=4; R(F)=0.048, Rw(F)=0.046 for 4135 reflections and 668 parameters. The two independent Mo complex anions in the structure show MoO distances of 1.62(1) and 1.629(9) Å. The fluorescence spectrum of the solid complex is similar in shape and intensity to those of other salts of MovOBr4(H2O)− with non-quenching cations. The relatively intense fluorescence of solid (BV)[MoOBr4(H2O)]Br·CH3CN suggests that electron transfer from MovOBr4(H2O)−*(2E) to BV2+, although slightly favorable thermodynamically, does not compete effectively with its rapid fluorescence." @default.
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• W2058545787 date "1994-11-01" @default.
• W2058545787 modified "2023-09-25" @default.
• W2058545787 title "Crystal structure and solid-state fluorescence of an oxomolybdenum(V)-benzylviologen electron donor-acceptor salt" @default.
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• W2058545787 doi "https://doi.org/10.1016/0020-1693(94)04067-2" @default.
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