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• W2058551344 abstract "Theoretical methods are described for the calculation of rovibrational levels of symmetric non-rigid triatomics using the symmetric hyperspherical coordinates of Smith and Whitten. An adiabatic separation of radial and angular motion is shown to be valid for H+ 3. The adiabatic angular functions are chosen as a linear combination of products of angular-momentum eigenfunctions and specially developed hyperspherical basis functions. Corrections to the adiabatic approximation are included by Brillouin-Wigner perturbation theory. Results are given for the H+ 3 system. The present approach has the advantage that all symmetric arrangements are treated equivalently." @default.
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• W2058551344 date "1990-08-20" @default.
• W2058551344 modified "2023-10-17" @default.
• W2058551344 title "The rotational-vibrational spectrum of symmetric non-rigid triatomics in hyperspherical coordinates: the H⁺ ₃ molecule" @default.
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• W2058551344 doi "https://doi.org/10.1080/00268979000101491" @default.
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