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- W2058551713 abstract "Rotational-isomeric-state models have been used to describe the statistical conformations of cyclic oligomers of dimethylsiloxane possessing 8–20 skeletal bonds. The results are compared with similar calculations made on linear-chain molecules of dimethylsiloxane. Cyclic dimethylsiloxanes, [(CH3)2SiO]x, with x = 4–10, appear to be relatively rigid, compared with their linear-chain counterparts, and their average shape is disclike. For cyclic molecules possessing ≳ 50 skeletal bonds, the directional correlations between pairs of skeletal bonds approach those calculated for the corresponding open-chain molecules." @default.
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- W2058551713 date "1988-01-01" @default.
- W2058551713 modified "2023-10-16" @default.
- W2058551713 title "Statistical conformations of cyclic dimethylsiloxanes" @default.
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- W2058551713 doi "https://doi.org/10.1016/0032-3861(88)90193-0" @default.
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