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- W2058576670 abstract "Three framework silver-thioantimonates, K(3)Ag(9)Sb(4)S(12)(1), Rb(3)Ag(9)Sb(4)S(12)(2), and Cs(3)Ag(9)Sb(4)S(12)(3), and one layered silver-thioarsenate, CsAg(2)AsS(3)(4), have been synthesized solvothermally in the presence of thiophenol as a mineralizer. Compounds 1, 2, and 3 are isostructural and contain infinite silver-sulfur chains [Ag(9)S(12)](15-). These chains are connected to one another by the antimony atoms to generate wide channels along the [001] direction where the alkali metal cations reside. The structure of 4 consists of helical chains [Ag(2)S(3)](4-) linked by the arsenic atoms to form layers with potassium ions between the layers." @default.
- W2058576670 created "2016-06-24" @default.
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- W2058576670 date "2009-12-28" @default.
- W2058576670 modified "2023-10-11" @default.
- W2058576670 title "Syntheses and Characterization of a Series of Silver−Thioantimonates(III) and Thioarsenates(III) Containing Two Types of Silver−Sulfur Chains" @default.
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- W2058576670 doi "https://doi.org/10.1021/ic902084u" @default.
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