Matches in SemOpenAlex for { <https://semopenalex.org/work/W2058622653> ?p ?o ?g. }
- W2058622653 endingPage "15300" @default.
- W2058622653 startingPage "15295" @default.
- W2058622653 abstract "The effect of hydrostatic pressure (P) on the phase transitions of polystyrene-block-poly(n-pentyl methacrylate) copolymer [PS-b-PnPMA] was investigated with FTIR spectroscopy at various temperatures. The experiments were performed by using a specially designed pressure cell optimized for low-pressure regime (<100 bar) with a higher resolution (∼1 bar). The size of the closed loop consisting of both the lower disorder-to-order transition (LDOT) and the upper order-to-disorder transition (UODT) measured by FTIR spectroscopy becomes smaller with increasing P, consistent with results obtained from birefringence measurement. At lower temperatures with increasing P, the PS main chains are found to move before the PnPMA main chains. This is because the mobility of the PnPMA main chains is restricted due to the cluster formation of the alkyl side chain. At higher temperatures, the PnPMA block chains are more mobile than the PS block chains due to their larger specific volumes. The results indicate that the LDOT is mainly affected by a favorable directional interaction between PS and PnPMA blocks due to the cluster formation of the alkyl side chain, whereas the UODT depends on the combinatorial entropy." @default.
- W2058622653 created "2016-06-24" @default.
- W2058622653 creator A5016291864 @default.
- W2058622653 creator A5028265103 @default.
- W2058622653 creator A5058649843 @default.
- W2058622653 creator A5090428415 @default.
- W2058622653 date "2008-11-01" @default.
- W2058622653 modified "2023-09-27" @default.
- W2058622653 title "Hydrostatic Pressure Effect on the Phase Transitions of a Closed-Loop Type Block Copolymer by Using 2D FTIR Correlation Spectroscopy" @default.
- W2058622653 cites W179543256 @default.
- W2058622653 cites W1963785881 @default.
- W2058622653 cites W1966543375 @default.
- W2058622653 cites W1967349548 @default.
- W2058622653 cites W1975372451 @default.
- W2058622653 cites W1983866015 @default.
- W2058622653 cites W1985635711 @default.
- W2058622653 cites W2003561442 @default.
- W2058622653 cites W2007829833 @default.
- W2058622653 cites W2008257760 @default.
- W2058622653 cites W2011340133 @default.
- W2058622653 cites W2015601713 @default.
- W2058622653 cites W2016887376 @default.
- W2058622653 cites W2021158547 @default.
- W2058622653 cites W2029913948 @default.
- W2058622653 cites W2034501059 @default.
- W2058622653 cites W2035086935 @default.
- W2058622653 cites W2035968908 @default.
- W2058622653 cites W2043674453 @default.
- W2058622653 cites W2046048926 @default.
- W2058622653 cites W2052795556 @default.
- W2058622653 cites W2053883254 @default.
- W2058622653 cites W2056217939 @default.
- W2058622653 cites W2057947601 @default.
- W2058622653 cites W2062211668 @default.
- W2058622653 cites W2066512404 @default.
- W2058622653 cites W2072088488 @default.
- W2058622653 cites W2085213610 @default.
- W2058622653 cites W2085610516 @default.
- W2058622653 cites W2104903817 @default.
- W2058622653 cites W2111443216 @default.
- W2058622653 cites W2137341285 @default.
- W2058622653 cites W2144943163 @default.
- W2058622653 cites W2145098987 @default.
- W2058622653 cites W2160346293 @default.
- W2058622653 cites W2161489535 @default.
- W2058622653 cites W2172949807 @default.
- W2058622653 cites W2490526535 @default.
- W2058622653 doi "https://doi.org/10.1021/jp806019n" @default.
- W2058622653 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18975883" @default.
- W2058622653 hasPublicationYear "2008" @default.
- W2058622653 type Work @default.
- W2058622653 sameAs 2058622653 @default.
- W2058622653 citedByCount "7" @default.
- W2058622653 countsByYear W20586226532012 @default.
- W2058622653 countsByYear W20586226532013 @default.
- W2058622653 countsByYear W20586226532016 @default.
- W2058622653 crossrefType "journal-article" @default.
- W2058622653 hasAuthorship W2058622653A5016291864 @default.
- W2058622653 hasAuthorship W2058622653A5028265103 @default.
- W2058622653 hasAuthorship W2058622653A5058649843 @default.
- W2058622653 hasAuthorship W2058622653A5090428415 @default.
- W2058622653 hasConcept C113196181 @default.
- W2058622653 hasConcept C120665830 @default.
- W2058622653 hasConcept C121332964 @default.
- W2058622653 hasConcept C122865956 @default.
- W2058622653 hasConcept C125743686 @default.
- W2058622653 hasConcept C149288129 @default.
- W2058622653 hasConcept C15920480 @default.
- W2058622653 hasConcept C159985019 @default.
- W2058622653 hasConcept C160892712 @default.
- W2058622653 hasConcept C178790620 @default.
- W2058622653 hasConcept C185592680 @default.
- W2058622653 hasConcept C188027245 @default.
- W2058622653 hasConcept C192562407 @default.
- W2058622653 hasConcept C204921945 @default.
- W2058622653 hasConcept C2777922577 @default.
- W2058622653 hasConcept C2780263894 @default.
- W2058622653 hasConcept C2910081258 @default.
- W2058622653 hasConcept C32891209 @default.
- W2058622653 hasConcept C44280652 @default.
- W2058622653 hasConcept C521977710 @default.
- W2058622653 hasConcept C62520636 @default.
- W2058622653 hasConcept C97355855 @default.
- W2058622653 hasConceptScore W2058622653C113196181 @default.
- W2058622653 hasConceptScore W2058622653C120665830 @default.
- W2058622653 hasConceptScore W2058622653C121332964 @default.
- W2058622653 hasConceptScore W2058622653C122865956 @default.
- W2058622653 hasConceptScore W2058622653C125743686 @default.
- W2058622653 hasConceptScore W2058622653C149288129 @default.
- W2058622653 hasConceptScore W2058622653C15920480 @default.
- W2058622653 hasConceptScore W2058622653C159985019 @default.
- W2058622653 hasConceptScore W2058622653C160892712 @default.
- W2058622653 hasConceptScore W2058622653C178790620 @default.
- W2058622653 hasConceptScore W2058622653C185592680 @default.
- W2058622653 hasConceptScore W2058622653C188027245 @default.
- W2058622653 hasConceptScore W2058622653C192562407 @default.
- W2058622653 hasConceptScore W2058622653C204921945 @default.
- W2058622653 hasConceptScore W2058622653C2777922577 @default.