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W2058626863 abstract "Abstract Starting from tricyclic lactam 2 , which is easily accessible by cyclocondensation of δ‐oxoester 1 with ( R )‐phenylglycinol, a three‐step synthetic route to enantiopure 1‐substituted tetrahydroisoquinolines, including 1‐alkyl‐, 1‐aryl‐, and 1‐benzyltetrahydroisoquinoline alkaloids, as well as the tricyclic alkaloid (–)‐crispine A, has been developed. The key step is a stereoselective α‐amidoalkylation reaction using the appropriate Grignard reagent." @default.
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W2058626863 date "2010-07-01" @default.
W2058626863 modified "2023-10-12" @default.
W2058626863 title "A General Methodology for the Enantioselective Synthesis of 1‐Substituted Tetrahydroisoquinoline Alkaloids" @default.
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W2058626863 doi "https://doi.org/10.1002/ejoc.201000473" @default.
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