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• W2058631957 abstract "To strengthen interfacial adhesion between selective carbon molecular sieve (CMS) layers and α-Al2O3 substrates, mordenite framework inverted (MFI)-type intermediate layers were synthesized to reduce pore sizes and improve chemical characteristics of underlying substrates and consequently facilitate formation of CMS layers. MFI-type zeolite intermediate layers were prepared on α-Al2O3 substrates via secondary growth of seeds to form polycrystalline zeolite layers with a-oriented crystallites. These crystallites increased cross-link strength between separation layers as well as gas pair separation performance. When a porous substrate was treated with silica seeds and covered with an MFI intermediate layer, CMS selectivity for H2/CH4 increased to 260.9 with permeability towards H2 of 2224 Barrer. These modifications improved the mechanical stability of CMS layers and will assist in their commercialization." @default.
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• W2058631957 date "2013-11-01" @default.
• W2058631957 modified "2023-10-15" @default.
• W2058631957 title "Effect of MFI zeolite intermediate layers on gas separation performance of carbon molecular sieve (CMS) membranes" @default.
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• W2058631957 doi "https://doi.org/10.1016/j.memsci.2013.06.051" @default.
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