Matches in SemOpenAlex for { <https://semopenalex.org/work/W2058676670> ?p ?o ?g. }
- W2058676670 endingPage "194" @default.
- W2058676670 startingPage "189" @default.
- W2058676670 abstract "The π-allyl(carbonyl)rhodium(I) complex [Rh(η3-C3H5)(CO)(κ2-iPr2PCH2PiPr2)] (2), which was obtained from [Rh(η3-C3H5)(κ2-iPr2PCH2PiPr2)] (1) and CO, reacted with H2 at room temperature to give the dinuclear hydrido compound [{Rh(CO)(μ-H)(μ-iPr2PCH2PiPr2)}2] (3) in nearly quantitative yield. The X-ray crystal structure analysis of 3 confirmed a distorted square-planar coordination sphere around both metal centers with one hydride and the CO group as well as the two phosphorus atoms of the bis(phosphino)methane ligands in trans disposition. The reaction of 1 with excess methylformiate led to the formation of the μ-carbonato complex [{Rh(CO)(μ-iPr2PCH2PPr2)}2(μ-O2CO)] (4) with an A-frame type skeleton. The carbonate ligand is possibly formed from HCO2Me by initial C–H cleavage and subsequent hydrolysis of the resulting CO2Me unit." @default.
- W2058676670 created "2016-06-24" @default.
- W2058676670 creator A5015897316 @default.
- W2058676670 creator A5026369423 @default.
- W2058676670 creator A5047134747 @default.
- W2058676670 creator A5083976317 @default.
- W2058676670 creator A5086562220 @default.
- W2058676670 date "1998-10-01" @default.
- W2058676670 modified "2023-10-03" @default.
- W2058676670 title "Two dinuclear rhodium complexes with a non-A-frame and a distorted A-frame skeleton and two iPr2PCH2PiPr2 molecules as bridging ligands" @default.
- W2058676670 cites W179089578 @default.
- W2058676670 cites W1971590170 @default.
- W2058676670 cites W1972120679 @default.
- W2058676670 cites W1972714347 @default.
- W2058676670 cites W1973479442 @default.
- W2058676670 cites W1985042937 @default.
- W2058676670 cites W1985197193 @default.
- W2058676670 cites W1996226905 @default.
- W2058676670 cites W2000377033 @default.
- W2058676670 cites W2022440614 @default.
- W2058676670 cites W2027043893 @default.
- W2058676670 cites W2037222426 @default.
- W2058676670 cites W2037345410 @default.
- W2058676670 cites W2046461306 @default.
- W2058676670 cites W2059125981 @default.
- W2058676670 cites W2059401704 @default.
- W2058676670 cites W2064791099 @default.
- W2058676670 cites W2067595475 @default.
- W2058676670 cites W2074664906 @default.
- W2058676670 cites W2075508712 @default.
- W2058676670 cites W2079250821 @default.
- W2058676670 cites W2081298333 @default.
- W2058676670 cites W2086524402 @default.
- W2058676670 cites W2089003232 @default.
- W2058676670 cites W2094079674 @default.
- W2058676670 cites W2135620202 @default.
- W2058676670 cites W2135865437 @default.
- W2058676670 cites W2148066840 @default.
- W2058676670 cites W228982257 @default.
- W2058676670 cites W2950766323 @default.
- W2058676670 cites W2952015943 @default.
- W2058676670 cites W2952886118 @default.
- W2058676670 cites W3137233485 @default.
- W2058676670 cites W3137877505 @default.
- W2058676670 cites W349660065 @default.
- W2058676670 cites W4237288762 @default.
- W2058676670 cites W2140468432 @default.
- W2058676670 doi "https://doi.org/10.1016/s0022-328x(98)00787-6" @default.
- W2058676670 hasPublicationYear "1998" @default.
- W2058676670 type Work @default.
- W2058676670 sameAs 2058676670 @default.
- W2058676670 citedByCount "11" @default.
- W2058676670 countsByYear W20586766702012 @default.
- W2058676670 countsByYear W20586766702017 @default.
- W2058676670 crossrefType "journal-article" @default.
- W2058676670 hasAuthorship W2058676670A5015897316 @default.
- W2058676670 hasAuthorship W2058676670A5026369423 @default.
- W2058676670 hasAuthorship W2058676670A5047134747 @default.
- W2058676670 hasAuthorship W2058676670A5083976317 @default.
- W2058676670 hasAuthorship W2058676670A5086562220 @default.
- W2058676670 hasConcept C11111787 @default.
- W2058676670 hasConcept C115624301 @default.
- W2058676670 hasConcept C116569031 @default.
- W2058676670 hasConcept C155647269 @default.
- W2058676670 hasConcept C161790260 @default.
- W2058676670 hasConcept C170493617 @default.
- W2058676670 hasConcept C178790620 @default.
- W2058676670 hasConcept C185592680 @default.
- W2058676670 hasConcept C2777961443 @default.
- W2058676670 hasConcept C32909587 @default.
- W2058676670 hasConcept C521398313 @default.
- W2058676670 hasConcept C544153396 @default.
- W2058676670 hasConcept C55493867 @default.
- W2058676670 hasConcept C71240020 @default.
- W2058676670 hasConcept C8010536 @default.
- W2058676670 hasConceptScore W2058676670C11111787 @default.
- W2058676670 hasConceptScore W2058676670C115624301 @default.
- W2058676670 hasConceptScore W2058676670C116569031 @default.
- W2058676670 hasConceptScore W2058676670C155647269 @default.
- W2058676670 hasConceptScore W2058676670C161790260 @default.
- W2058676670 hasConceptScore W2058676670C170493617 @default.
- W2058676670 hasConceptScore W2058676670C178790620 @default.
- W2058676670 hasConceptScore W2058676670C185592680 @default.
- W2058676670 hasConceptScore W2058676670C2777961443 @default.
- W2058676670 hasConceptScore W2058676670C32909587 @default.
- W2058676670 hasConceptScore W2058676670C521398313 @default.
- W2058676670 hasConceptScore W2058676670C544153396 @default.
- W2058676670 hasConceptScore W2058676670C55493867 @default.
- W2058676670 hasConceptScore W2058676670C71240020 @default.
- W2058676670 hasConceptScore W2058676670C8010536 @default.
- W2058676670 hasIssue "1-2" @default.
- W2058676670 hasLocation W20586766701 @default.
- W2058676670 hasOpenAccess W2058676670 @default.
- W2058676670 hasPrimaryLocation W20586766701 @default.
- W2058676670 hasRelatedWork W2012345717 @default.
- W2058676670 hasRelatedWork W2012675768 @default.
- W2058676670 hasRelatedWork W2067123649 @default.
- W2058676670 hasRelatedWork W2075817299 @default.