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- W2058682755 abstract "Abstract The 3‐miktoarm star‐shaped ABC copolymers of polystyrene–poly(ethylene oxide)–poly(ethoxyethyl glycidyl ether) (PS‐PEO‐PEEGE) and polystyrene–poly(ethylene oxide)–polyglycidol (PS‐PEO‐PG) with low polydispersity indices (PDI ≤ 1.12) and controlled molecular weight were synthesized by a combination of anionic polymerization with ring‐opening polymerization. The polystyryl lithium (PS − Li + ) was capped by EEGE firstly to form the functionalized polystyrene (PS A ) with both an active ω ‐hydroxyl group and an ω ′‐ethoxyethyl‐protected hydroxyl group, and then the PS‐ b ‐PEO block copolymers, star(PS‐PEO‐PEEGE) and star(PS‐PEO‐PG) copolymers were obtained by the ring‐opening polymerization of EO and EEGE respectively via the variation of the functional end group, and then the hydrolysis of the ethoxyethyl group on the PEEGE arm. The obtained star copolymers and intermediates were characterized by 1 H NMR spectroscopy and SEC. magnified image" @default.
- W2058682755 created "2016-06-24" @default.
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- W2058682755 date "2007-01-30" @default.
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- W2058682755 title "Preparation of Star‐Shaped ABC Copolymers of Polystyrene‐Poly(ethylene oxide)‐Polyglycidol Using Ethoxyethyl Glycidyl Ether as the Cap Molecule" @default.
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- W2058682755 doi "https://doi.org/10.1002/marc.200600740" @default.
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