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- W2058696871 abstract "A regio- and stereospecific total synthesis of (±)-methyl rishirilide B (2b), an (α)2-macroglobulin inhibitor, is described. A key feature of the synthetic plan was regiospecific construction of a hydroanthracenone intermediate through condensation of a phenylsulfonyl isobenzofuranone with a functionalized 2-cyclohexen-1-one. Introduction of the vicinal trans-hydroxyl groups in the densely functionalized A-ring was accomplished via a novel one-pot procedure that involved oxidation of enolate anions with the Davis reagent." @default.
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- W2058696871 date "2010-06-13" @default.
- W2058696871 modified "2023-09-25" @default.
- W2058696871 title "ChemInform Abstract: Total Synthesis of (.+-.)-Methyl Rishirilide B." @default.
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- W2058696871 doi "https://doi.org/10.1002/chin.199940201" @default.
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