FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2058705291> ?p ?o ?g. }

• W2058705291 endingPage "140" @default.
• W2058705291 startingPage "133" @default.
• W2058705291 abstract "Cu2+ and Co2+ complexes of adriamycin (ADM) in aqueous solutions have been examined using EPR spectroscopy. An appreciable amount of Cu2+ and Co2+ complexes formed in the solutions were found to be in the EPR silent associated form, where the metal ions are antiferromagnetically coupled. The associated form of the Cu2+ complex may be neither a simple dimer nor coordination polymer but aggregates of a stacked type. Formation of a complex having Cu2+-ADM stoichiometry of 1:2 was observed for the solutions containing excess of ADM as an EPR observable species. The complex having Cu2+-ADM stoichiometry of 1:1 was not observed directly by EPR, but the presence of the complex is undeniable, especially at low pH range so far as large excessive ADM is not present. The Co2+ complex of ADM observed by EPR is in the high-spin (S = 3/2) state and may have a coordination structure of tetragonal symmetry. The EPR spectra of these complexes apparently show that the Cu2+ and Co2+ ions are bound at the carbonyl and phenolate oxygen in the 1,4-dihydroxyanthraquinone moiety and the amino nitrogen in the sugar part does not seem to participate in the coordination to the metal ions." @default.
• W2058705291 created "2016-06-24" @default.
• W2058705291 creator A5090501074 @default.
• W2058705291 date "1987-06-01" @default.
• W2058705291 modified "2023-10-12" @default.
• W2058705291 title "EPR studies of copper(II) and cobalt(II) complexes of adriamycin" @default.
• W2058705291 cites W1485285680 @default.
• W2058705291 cites W1517318768 @default.
• W2058705291 cites W1778245994 @default.
• W2058705291 cites W1972048837 @default.
• W2058705291 cites W1975098194 @default.
• W2058705291 cites W1978331862 @default.
• W2058705291 cites W1993349215 @default.
• W2058705291 cites W1994913349 @default.
• W2058705291 cites W2004373248 @default.
• W2058705291 cites W2010593484 @default.
• W2058705291 cites W2019664243 @default.
• W2058705291 cites W2021586313 @default.
• W2058705291 cites W2022874322 @default.
• W2058705291 cites W2030529611 @default.
• W2058705291 cites W2039047059 @default.
• W2058705291 cites W2039178516 @default.
• W2058705291 cites W2042308398 @default.
• W2058705291 cites W2058563509 @default.
• W2058705291 cites W2083894855 @default.
• W2058705291 cites W2086503308 @default.
• W2058705291 cites W2111426313 @default.
• W2058705291 cites W2125891400 @default.
• W2058705291 cites W2412649009 @default.
• W2058705291 cites W2951955795 @default.
• W2058705291 doi "https://doi.org/10.1016/0162-0134(87)80049-1" @default.
• W2058705291 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/3037023" @default.
• W2058705291 hasPublicationYear "1987" @default.
• W2058705291 type Work @default.
• W2058705291 sameAs 2058705291 @default.
• W2058705291 citedByCount "26" @default.
• W2058705291 countsByYear W20587052912014 @default.
• W2058705291 countsByYear W20587052912015 @default.
• W2058705291 countsByYear W20587052912017 @default.
• W2058705291 countsByYear W20587052912018 @default.
• W2058705291 countsByYear W20587052912019 @default.
• W2058705291 countsByYear W20587052912020 @default.
• W2058705291 countsByYear W20587052912021 @default.
• W2058705291 countsByYear W20587052912023 @default.
• W2058705291 crossrefType "journal-article" @default.
• W2058705291 hasAuthorship W2058705291A5090501074 @default.
• W2058705291 hasConcept C115624301 @default.
• W2058705291 hasConcept C121332964 @default.
• W2058705291 hasConcept C144082473 @default.
• W2058705291 hasConcept C145148216 @default.
• W2058705291 hasConcept C147789679 @default.
• W2058705291 hasConcept C170751736 @default.
• W2058705291 hasConcept C178790620 @default.
• W2058705291 hasConcept C179104552 @default.
• W2058705291 hasConcept C184651966 @default.
• W2058705291 hasConcept C185592680 @default.
• W2058705291 hasConcept C187961010 @default.
• W2058705291 hasConcept C199164860 @default.
• W2058705291 hasConcept C2776568683 @default.
• W2058705291 hasConcept C2779546866 @default.
• W2058705291 hasConcept C46141821 @default.
• W2058705291 hasConcept C515602321 @default.
• W2058705291 hasConcept C544153396 @default.
• W2058705291 hasConcept C544778455 @default.
• W2058705291 hasConcept C71240020 @default.
• W2058705291 hasConcept C8010536 @default.
• W2058705291 hasConceptScore W2058705291C115624301 @default.
• W2058705291 hasConceptScore W2058705291C121332964 @default.
• W2058705291 hasConceptScore W2058705291C144082473 @default.
• W2058705291 hasConceptScore W2058705291C145148216 @default.
• W2058705291 hasConceptScore W2058705291C147789679 @default.
• W2058705291 hasConceptScore W2058705291C170751736 @default.
• W2058705291 hasConceptScore W2058705291C178790620 @default.
• W2058705291 hasConceptScore W2058705291C179104552 @default.
• W2058705291 hasConceptScore W2058705291C184651966 @default.
• W2058705291 hasConceptScore W2058705291C185592680 @default.
• W2058705291 hasConceptScore W2058705291C187961010 @default.
• W2058705291 hasConceptScore W2058705291C199164860 @default.
• W2058705291 hasConceptScore W2058705291C2776568683 @default.
• W2058705291 hasConceptScore W2058705291C2779546866 @default.
• W2058705291 hasConceptScore W2058705291C46141821 @default.
• W2058705291 hasConceptScore W2058705291C515602321 @default.
• W2058705291 hasConceptScore W2058705291C544153396 @default.
• W2058705291 hasConceptScore W2058705291C544778455 @default.
• W2058705291 hasConceptScore W2058705291C71240020 @default.
• W2058705291 hasConceptScore W2058705291C8010536 @default.
• W2058705291 hasIssue "2" @default.
• W2058705291 hasLocation W20587052911 @default.
• W2058705291 hasLocation W20587052912 @default.
• W2058705291 hasOpenAccess W2058705291 @default.
• W2058705291 hasPrimaryLocation W20587052911 @default.
• W2058705291 hasRelatedWork W1516735584 @default.
• W2058705291 hasRelatedWork W1585447513 @default.
• W2058705291 hasRelatedWork W1654479263 @default.
• W2058705291 hasRelatedWork W1981011544 @default.
• W2058705291 hasRelatedWork W2031633929 @default.
• W2058705291 hasRelatedWork W2082337540 @default.
• W2058705291 hasRelatedWork W2084916282 @default.

• next