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• W2058719947 abstract "A series of isoxazolo[5,4-b]pyridin-6(7H)-ones (8) have been prepared with a high stereochemical control from the novel 3,4-dihydro-2(1H)-pyridones (7) by reaction with hydroxylamine hydrochloride and subsequent 5-endo-trig cyclization. A structural study by X-ray analyses and theoretical calculations (AM1) of both heterocyclic systems (7 and 8) shows a favoured conformer with the aryl group on C4 in a pseudoaxial position. The same favoured conformation was found in solution according to NOE experiments and comparison of theoretical and experimental coupling constants." @default.
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• W2058719947 date "2000-06-01" @default.
• W2058719947 modified "2023-10-04" @default.
• W2058719947 title "Synthesis and Structural Study of 3,4-Dihydro-2(1H)-pyridones and Isoxazolo[5,4-b]pyridin-6(7H)-ones" @default.
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• W2058719947 doi "https://doi.org/10.1002/1099-0690(200006)2000:11<2079::aid-ejoc2079>3.0.co;2-#" @default.
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