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- W2058737043 abstract "A single-crystal X-ray study of a hydrogen-treated TeNaX catalyst has revealed scattering matter, assigned to telluride ion on the basis of chemical environment, in both the sodalite cage and the supercage of the X-zeolite structure. Both telluride ion sites have relatively low occupancy factors. The telluride ion in the center of the sodalite cage is coordinated to four site I′ and possibly to four site II′ sodium ions. The supercage telluride ion is coordinated to a site II sodium ion and, probably, to at least one additional sodium ion (not detected) located near the conventional site III. The chemical involvement of hydrogen, necessary for the reduction of tellurium, is supported by diffuse reflectance spectra and hydrogen sorption data. Probable hydrogen locations on the zeolitic framework are assigned." @default.
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- W2058737043 date "1972-01-01" @default.
- W2058737043 modified "2023-10-03" @default.
- W2058737043 title "Tellurium-loaded zeolites. III. The structure of Te/NaX" @default.
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- W2058737043 doi "https://doi.org/10.1016/0021-9517(72)90020-6" @default.
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