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- W2058748037 abstract "Cu/SiO2 cogelled xerogel catalysts were synthesized by cogelation of tetraethoxysilane (TEOS) and chelates of Cu with 3-(2-aminoethylamino)-propyltrimethoxysilane (EDAS). The resulting catalysts are composed of metallic crystallites with a diameter of about 3 nm located inside microporous silica particles and larger metallic particles with a diameter of 8–30 nm located outside silica network. Cu/SiO2 catalysts were tested for 2-butanol dehydrogenation. This reaction over Cu/SiO2 cogelled xerogel catalysts is a structure-sensitive reaction: large metallic particles located outside silica particles are responsible for the dehydrogenation reaction, while small metallic particles located inside silica particles do not participate to the reaction." @default.
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- W2058748037 date "2007-12-01" @default.
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- W2058748037 title "On the structure-sensitivity of 2-butanol dehydrogenation over Cu/SiO2 cogelled xerogel catalysts" @default.
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- W2058748037 doi "https://doi.org/10.1016/j.catcom.2007.04.004" @default.
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