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• W2058754293 abstract "The enantiomers of 3,3′-spirobi(3-selenaphthalide) (2) were obtained via direct separation by liquid chromatography on a chiral stationary phase. Determination of the absolute configuration was made by X-ray crystallography with the use of the anomalous dispersion technique. The first eluted (+)-form (λ = 302 and 365 nm) of 2 was found to have (S)-configuration. By a comparison of CD-spectra, the same (S)-configuration could be assigned to the (+)-forms of the sulfur (1) and tellurium (7) analogs of 2. An asymmetric dichloro-substituted spirobilactone (4) was also synthesized and separated into its enantiomers. Relative configurations between 4 and its parent compound (3) were established from the corresponding chiroptical data obtained. Chirality 12: 71–75, 2000. © 2000 Wiley-Liss, Inc." @default.
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• W2058754293 date "2000-01-01" @default.
• W2058754293 modified "2023-10-18" @default.
• W2058754293 title "Absolute configuration of a diaryldiacyloxy spiroselenurane and resolution of a carbon analog" @default.
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• W2058754293 doi "https://doi.org/10.1002/(sici)1520-636x(2000)12:2<71::aid-chir3>3.0.co;2-s" @default.
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