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- W2058756073 abstract "A series of thioacetyl-functionalized fullerene-C60 derivatives were synthesized using the Prato reaction of fullerene-C60 with six different 4-(S-acetylthioalkyl)benzaldehydes. The structures of the synthesized compounds were characterized by FT-IR, 1H NMR and ESI-MS techniques. The LUMO–HOMO band gaps, derived from DFT B3LYP/6-31G* calculations, for the azomethine ylides corresponding to each 4-(S-acetylthioalkyl)benzaldehyde and fullerene-C60 were correlated with the efficiency of the Prato reaction. The compounds were deposited onto gold electrodes via self-assembly following an in situ deprotection procedure which transformed the thioacetyl-functionalized compounds into their thiolated derivatives. The redox properties of the C60 derivatives in solution were characterized using Voltammetry. The LUMO–HOMO band gaps obtained from the electrochemical data were compared with the density functional theory (DFT) values for the optimized structures. The thioacetyl-functionalized C60 derivatives were employed for the catalytic reduction of halogenated hydrocarbons. Following deprotection, they were also employed for the modification of gold substrates. The solvent dependent barrier properties of the thiolated fullerene films were investigated using Cyclic Voltammetry (CV) and Electrochemical Impedance Spectroscopy (EIS). The topography of the C60 derivative modified electrode was investigated using X-ray Photoelectron Spectroscopy (XPS) and Atomic Force Microscopy (AFM), which confirmed stable modification of the Au support with a three dimensional (3D) film of worm-like fullerene aggregates." @default.
- W2058756073 created "2016-06-24" @default.
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- W2058756073 date "2014-01-01" @default.
- W2058756073 modified "2023-10-16" @default.
- W2058756073 title "Nanostructured films of in situ deprotected thioacetyl-functionalized C60-fullerenes on a gold surface" @default.
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- W2058756073 doi "https://doi.org/10.1039/c3ta13844e" @default.
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