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- W2058756270 abstract "The hydroaminomethylation (hydroformylation/reductive amination) of the naturally occurring monoterpenes, i.e., limonene, camphene, and β-pinene, was studied having as condensation counterparts the amines di-n-butylamine, morpholine or n-butylamine. Moderate to good yields (75–94%) were obtained employing [Rh(cod)(μ-OMe)]2 as pre-catalyst in the presence or not of triphenylphosphine or tribenzylphosphine as ancillaries in toluene, at 100 °C and 60 bar of an equimolar mixture of carbon monoxide and hydrogen. Some of the hydroaminomethylation products derived from limonene have biological activity and the products derived from camphene and β-pinene are new." @default.
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- W2058756270 date "2012-01-01" @default.
- W2058756270 modified "2023-10-16" @default.
- W2058756270 title "An efficient method for the transformation of naturally occurring monoterpenes into amines through rhodium-catalyzed hydroaminomethylation" @default.
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- W2058756270 doi "https://doi.org/10.1016/j.apcata.2011.10.021" @default.
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