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- W2058772754 abstract "Rhenium 4f and chlorine 2p electron binding energies have been recorded for a series of complex halides of rhenium in the formal oxidation states +4 and +3. Referencing the rhenium 4f7//2 level to a standard chlorine 2p value provides a guide to the metal oxidation state and allows a ‘correction’ to be made for small variations in Madelung potential within a series of salts of a particular complex halide (e.g., Re2Cl82–). Both bridging and terminal rhenium-chlorine atoms have been distinguished in the [Re2Cl9]– and [Re2Cl9]2– anions. Little variation in rhenium 4f binding energies was observed for a series of anions of the type [ReCl5,L]–. The rhenium 4f binding energies of the Re(NCS)62– and Re2(NCS)82– anions are also reported together with the nitrogen 1s and sulphur 2p levels of the pseudohalide ligand molecules." @default.
- W2058772754 created "2016-06-24" @default.
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- W2058772754 date "1973-01-01" @default.
- W2058772754 modified "2023-09-23" @default.
- W2058772754 title "Complex halides of the transition metals. Part XIV. The X-ray photoelectron spectra of mononuclear and dinuclear complex halides of rhenium(III) and rhenium(IV), and of the Re(NCS)6 2? and Re2(NCS)8 2? complex anions" @default.
- W2058772754 doi "https://doi.org/10.1039/dt9730001039" @default.
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