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- W2058777794 abstract "The first synthesis of dolabelide C (1), a cytotoxic marine macrolide, is reported utilizing a phosphate tether-mediated approach. Bicyclic phosphates (S,S,SP)-5 and (R,R,RP)-5 serve as the central building blocks for the construction of two major 1,3-anti-diol subunits in 1 through selective cleavage pathways, regioselective olefin reduction, and cross-metathesis. Overall, phosphate-mediated processes provided copious amounts of both major subunits allowing for a detailed RCM macrocyclization study to the 24-membered macrolactone 1." @default.
- W2058777794 created "2016-06-24" @default.
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- W2058777794 date "2011-04-29" @default.
- W2058777794 modified "2023-10-03" @default.
- W2058777794 title "Total Synthesis of Dolabelide C: A Phosphate-Mediated Approach" @default.
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- W2058777794 doi "https://doi.org/10.1021/jo2003506" @default.
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