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- W2058786622 abstract "Abstract Water sorption isotherms for a pure rutile have been measured at five temperatures between 18 and 35°C in the region of relative pressure 0.03 to 0.40. Each isotherm has two turning points (knees) at relative pressures of 0.03 and 0.22. The isosteric heats of adsorption decrease linearly with increasing coverage between these knees, but then fall to a value close to the heat of liquefaction. The differential entropies of adsorption are negative below the second knee, close to zero at this knee and positive at higher coverages. This is taken as confirmation that the second knee marks the completion of adsorption of a close-packed monomolecular water layer." @default.
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- W2058786622 date "1974-01-01" @default.
- W2058786622 modified "2023-09-27" @default.
- W2058786622 title "The differential enthalpies and entropies of adsorption of water vapor on rutile at 25°C in the region of monolayer coverage" @default.
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- W2058786622 doi "https://doi.org/10.1016/0021-9797(74)90020-4" @default.
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