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- W2058792291 abstract "Abstract A mixed ionic liquid system has been developed for the efficient catalysis of CO2 addition to aliphatic epoxides without involving any transition metal catalysts or other additives. The ionic liquid integrated with pyridinium and pyrrolidinium groups (1·(Br)3) together with a non-polar ionic liquid (3·(Ntf)2) effectively transformed non-polar aliphatic epoxides to cyclic carbonates by the reaction with CO2 under mild CO2 pressure (3.0 MPa) and reaction temperature (80 °C). The presence of 3·(Ntf)2 remarkably improved the catalytic activity of 1·(Br)3 towards non-polar epoxides by increasing the miscibility of catalyst with the substrates. The mixed ionic liquid system is robust enough to be recycled without any significant loss of catalytic activity. GC–MS studies were performed to reveal the reaction pathways to the cyclic carbonates and a feasible model accounting for the effective CO2 activation in the ionic liquid system was proposed using density functional theory (DFT) calculations." @default.
- W2058792291 created "2016-06-24" @default.
- W2058792291 creator A5003602671 @default.
- W2058792291 creator A5028129738 @default.
- W2058792291 creator A5029866664 @default.
- W2058792291 creator A5029932972 @default.
- W2058792291 creator A5054639075 @default.
- W2058792291 creator A5079956622 @default.
- W2058792291 date "2014-02-01" @default.
- W2058792291 modified "2023-10-13" @default.
- W2058792291 title "A green catalysis of CO2 fixation to aliphatic cyclic carbonates by a new ionic liquid system" @default.
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