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• W2058820560 abstract "The first four perturbation coefficients in the expansion of the Helmholtz free energy in power series of the inverse of the reduced temperature for a number of potential models with hard-sphere cores plus core-softened and discontinuous tails are obtained from Monte Carlo simulations. The potential models considered include square-well, double square-well, and square-shoulder plus square-well, with different potential parameters. These simulation data are used to evaluate the performance of a traditional macroscopic compressibility approximation (MCA) for the second order coefficient and a recent coupling parameter series expansion (CPSE) for the first four coefficients. Comprehensive comparison indicates the incapability of the MCA for the second order coefficient in most non-stringent situations, and significance of the CPSE in accurately calculating these four coefficients." @default.
• W2058820560 created "2016-06-24" @default.
• W2058820560 creator A5067939474 @default.
• W2058820560 creator A5079053274 @default.
• W2058820560 date "2013-06-28" @default.
• W2058820560 modified "2023-10-16" @default.
• W2058820560 title "Monte Carlo and theoretical calculations of the first four perturbation coefficients in the high temperature series expansion of the free energy for discrete and core-softened potential models" @default.
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• W2058820560 doi "https://doi.org/10.1063/1.4811285" @default.
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