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- W2058876851 abstract "In order to solidify the electrochemiluminescence (ECL) luminophor tris(2,2'-bipyridyl) ruthenium(II) ([Ru(bpy)(3)](2+)) onto the electrode surfaces robustly, the negative charged heteropolyacids (HPAs) moieties were utilized to attract and bond cations [Ru(bpy)(3)](2+) via an adsorption method. The compositions and microstructures of the hybrid complexes were characterized by elemental analysis (EDS), spectroscopic techniques (UV-vis, FTIR) and field-emission scanning electron microscopy (FE-SEM). The electrochemical and ECL behaviors of the [Ru(bpy)(3)](2+)/[PW(12)O(40)](3-) hybrid complex contained in the solid film of the nanocomposites formed on the electrode surfaces were also studied. It was found that the corresponding solid membranes exhibited a diffusion-controlled voltammetric feature and excellent electrochemiluminescence behaviors. Hence potential prospects as new electrochemiluminescent materials for application in electroanalytical detection are envisioned." @default.
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- W2058876851 date "2009-12-15" @default.
- W2058876851 modified "2023-09-27" @default.
- W2058876851 title "[Ru(bpy)3]2+ nanocomposites containing heteropolyacids: Simple preparation and stable solid-state electrochemiluminescence detection application" @default.
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- W2058876851 doi "https://doi.org/10.1016/j.talanta.2009.08.008" @default.
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