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- W2058880048 abstract "Abstract Aus Diphenylphosphanoxid (C 6 H 5 ) 2 P(O)H ( 1 ) erhält man mit aktiviertem Triethylboran ( 2a *) das Derivat (C 6 H 5 ) 2 POB(C 2 H 5 ) 2 ( 3′a ). Aus 3′a sind mit Tetraalkyldiboranen(6) (R 2 BH) 2 [RC 2 H 5 : ( 4a ) 2 ; RC 3 H 7 : ( 4b ) 2 ] die BH 3 ‐Additionsverbindungen (C 6 H 5 ) 2 P(BH 3 )OBR 2 [RC 2 H 5 : 3′a –BH 3 ], [(C 6 H 5 ) 2 P(BH 3 )‐O] 2 BR [RC 2 H 5 : 5a –(BH 3 ) 2 ] und [(C 6 H 5 ) 2 P(BH 3 )O] 3 B [ 6 –(BH 3 ) 3 ] zugänglich. Bis(9‐borabicyclo[3.3.1]nona) ( 4c ) 2 und 1 reagieren unter Bildung von (C 6 H 5 )POBC 8 H 14 ( 3′c ) oder 3′c – 4c und (C 6 H 5 PH–HBC 8 H 14 ( 7 – 4c ). Das kristallisierte zwitterionische (C 6 H 5 ) 2 P(H)OB[OP(BH 3 )‐" @default.
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- W2058880048 date "1987-07-01" @default.
- W2058880048 modified "2023-10-16" @default.
- W2058880048 title "Reaktionen des Diphenylphosphanoxids mit Organodiboranen(6) – Struktur einer zwitterionischen –POB– ‐Verbindung <sup>1)</sup>" @default.
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- W2058880048 doi "https://doi.org/10.1002/cber.19871200708" @default.
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