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- W2058902332 abstract "Solution studies (pH and 1H NMR titrations) on Zn2+ complexes 1 and 2 derived from N′,N″,N″′-tris(3-aminopropyl)amine L1 and N′,N″,N″′-tris(3-dimethyl-aminopropyl)amine L2 revealed that the presence of the hydrophobic (methyl) groups attached to the tripodal ligand side arms decreased the pKa of Zn-bound water molecule from 9.99 for 1 to 8.01 for 2, respectively. The X-ray diffraction studies have established the structures [L1Zn](ClO4)2 1 and [L1Zn(DETP)](ClO4) 3, DETP−=O,O-diethyl thiophospate. Compound 1 consists of a monomeric cation and ClO4 − counter ions. The coordination geometry of the Zn(II) centers may be described as distorted tetrahedral. Whereas in compound 3 the zinc atom adopts the slightly distorted trigonal-bipyramidal coordination geometry with the three primary nitrogen's on the basal plane and the tertiary nitrogen and the oxygen of DETP− at the apex. The hydroxo complexes [ZnL(OH)]+ species showed slight catalytic activity in the hydrolysis of the phosphotriester 2,4-dinitrophenyl diethyl phosphate." @default.
- W2058902332 created "2016-06-24" @default.
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- W2058902332 date "2003-09-01" @default.
- W2058902332 modified "2023-09-24" @default.
- W2058902332 title "Solution studies of N′,N″,N″′-tris(3-aminopropyl)amine-based zinc(II) complexes and X-ray crystal structures of [Zn(trpn)](ClO4)2 and [Zn(trpn)(DETP)]ClO4, DETP−=O,O-diethyl thiophospate. Catalytic activity of the complexes in the hydrolysis of the phosphotriester 2,4-dinitrophenyl diethyl phosphate" @default.
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- W2058902332 doi "https://doi.org/10.1016/s0020-1693(03)00239-1" @default.
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