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- W2058902906 abstract "Catalytic activities of perovskite-type mixed oxides (La1−xA′xMnO3, where A′ = Sr, Ce, Hf and x = 0–1.0) for oxidation of propane have been measured and they were compared with several properties of oxygen of the catalysts. It was found that the catalytic activity of La1−xSrxMnO3 varied in parallel with the reducibility of catalyst surface, the amount of reversibly adsorbed oxygen (static measurement and low-temperature peak of temperature-programmed desorption (TPD)), and the rate of isotopic equilibration of oxygen. However, the high-temperature peak of TPD was not correlated with the catalytic activity. The reasons for the parallel variation of these properties have been discussed on the basis of the possible nonstoichiometry and the surface properties of catalysts. Similar effects of Ce and Hf substitution were assumed to be due to the formation of cation vacancy at A site." @default.
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- W2058902906 title "Catalytic properties of La1−A′ MnO3 (A′ = Sr, Ce, Hf)" @default.
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