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W2058972201 abstract "We report solid-state 95Mo NMR of MoV, MoV,VI and MoVI species in mixed-valence polyoxomolybdates (V, VI) with localized or delocalized d1 electrons. Parameters about chemical shift and quadrupole interactions of 95Mo in diamagnetic crystals of [Me3NH]6[H2Mo12VO28(OH)12(MoVIO3)4]·2H2O(1) with localized electrons and [NMe4]2[NH4]8[(Mo6VIMoVO23)2]·8H2O(2) with delocalized ones were obtained by simulation of magic-angle-spinning (MAS) 95Mo NMR spectra. The isotropic and anisotropic chemical shifts of sites of MoV in 1 and MoV, VI in 2, respectively, exhibited absolute values quite larger than those of other MoVI sites, which is examined by quantum chemical calculations." @default.
W2058972201 created "2016-06-24" @default.
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W2058972201 date "2010-03-01" @default.
W2058972201 modified "2023-10-17" @default.
W2058972201 title "Solid-state 95Mo NMR of mixed-valence polyoxomolybdates (V, VI) with localized or delocalized <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML altimg=si62.gif display=inline overflow=scroll><mml:mrow><mml:msup><mml:mrow><mml:mtext>d</mml:mtext></mml:mrow><mml:mrow><mml:mn>1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math> electrons" @default.
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W2058972201 doi "https://doi.org/10.1016/j.cplett.2010.01.040" @default.
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