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- W2058972893 abstract "Thermodynamic analysis via simultaneous equations of previously reported mass spectra obtained from water vapor at 99 °C yielded ΔE, ΔH, and ΔV values for H-bond formation in large, ion-induced, charged, water clusters, H+(H2O)c, ranging from C ≈ 20 to C ≈ 45 H2O. An average ΔE value of −2190 ± 15 cal/mol H-bond was calculated for formation at pressures from ≈0.39 to ≈0.56 bar, as well as an approximate ΔH of −2540 ± 70 cal/mol H-bond. However, van't Hoff treatment of mass spectral data between 41 and 90 °C at a constant partial pressure of 0.038 bar yielded a more accurate ΔH of −2425 ± 25 cal/mol H-bond. Both ΔH's are in close agreement with H-bond ΔH's from Raman, infrared, and viscosity data for liquid water, despite the fact that they refer to charged water clusters. A ΔV value of −31 300 ± 1000 cm3/mol H-bond also resulted from the simultaneous equations. This ΔV compares favorably with a limiting ΔV value of −30 790 cm3/mol H-bond corresponding to the condensation of steam to liquid water at 0.5 bar and 373.15 K. The ΔE, ΔH, ΔV, and ΔS values involved here demonstrate that the condensation of monomeric water onto large, charged, clusters in the vapor is analogous to the condensation of steam." @default.
- W2058972893 created "2016-06-24" @default.
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- W2058972893 date "2002-01-18" @default.
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- W2058972893 title "Energy, Enthalpy, and Volume Change of Hydrogen-Bond Formation in Large, Charged, Water Vapor Clusters, H<sup>+</sup>(H<sub>2</sub>O)<sub>c</sub>, Determined from Mass Spectral Distributions" @default.
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- W2058972893 doi "https://doi.org/10.1021/jp013612u" @default.
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