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- W2058976411 abstract "meso-(R,S)-Dithia[3.3]-paracyclophane S,S′-dioxide is formed with complete stereoselection by the thermolysis of 3,3′-[1,4-phenylene-bis(methylenesulfinyl)]-dipropanoate—that generates in situ two transient sulfenic acid functions—in the presence of p-diethynylbenzene. By employing an improved procedure that we have recently optimized, the title compound has been prepared in a 70% yield as a single diastereoisomer. A density functional B3LYP/6-311+G(d,p) study demonstrates that the final syn-addition cyclization step takes place under kinetic control, through a five-membered transition state that defines the stereochemistry of the resulting cyclophane." @default.
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- W2058976411 date "2014-09-01" @default.
- W2058976411 modified "2023-09-30" @default.
- W2058976411 title "Kinetic control in the formation of meso-dithia[3.3]-paracyclophane S,S′-dioxide" @default.
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- W2058976411 doi "https://doi.org/10.1016/j.tetlet.2014.07.082" @default.
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