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- W2058976434 abstract "Caffeine (1,3,7-trimethylxanthine) is a chemical substance associated with everyday human life. In order to recognize caffeine in water, six water-soluble acyclic phane compounds composed of three aromatic rings were examined as artificial receptors. 1H NMR titration experiments revealed that 6,6′-[1,3-phenylenebis(carbonylimino)]bis-1,3-naphthalenedisulfonate had the highest binding ability for caffeine, with a binding constant (Kb) of 127±5 M−1 at 300 K. While this phane compound also formed a complex with theophylline (1,3-dimethylxanthine) at around half the value of the binding constant for caffeine (Kb=64±4 M−1), it showed weak or little complexation for adenosine, guanosine, inosine, and their 5′-phosphates (sodium salts of adenylic acid, guanylic acid, and inosinic acid)." @default.
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- W2058976434 date "2014-01-01" @default.
- W2058976434 modified "2023-09-26" @default.
- W2058976434 title "Recognition of caffeine by a water-soluble acyclic phane compound" @default.
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- W2058976434 doi "https://doi.org/10.1016/j.tet.2013.12.035" @default.
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