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- W2058977237 abstract "Cyclohexadiene-1,3 and bicyclo[2.2.1]heptadiene-2,5 each (B) copolymerize with acrylonitrile (A) in bulk at 60 °C in the presence of 0.01 M benzoyl peroxide. The copolymerization parameters for cyclohexadiene-1,3 are r A = 0.026 ± 0.014,r B = 0.20 ± 0.01, Q B = 1.76, e B = −1.18; for bicycloheptadiene the parameters are r A = 0.65 ± 0.02, r B = 0.47 ± 0.08, Q B = 0.27, e B = 0.03; limits of error are given at the 10% probability level. Cycloheptatriene and cyclooctatetraene inhibit the polymerization of acrylonitrile under similar conditions over a wide range of concentration. These results are discussed in terms of the general reactivity of the cyclic polyenes and of the behavior of structurally related monomers in polymerization, and a consistent pattern of reactivity emerges." @default.
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- W2058977237 date "1964-11-01" @default.
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- W2058977237 title "THE REACTIVITY OF THE CYCLIC POLYENES TOWARDS FREE RADICALS: I. COPOLYMERIZATION WITH ACRYLONITRILE" @default.
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- W2058977237 doi "https://doi.org/10.1139/v64-375" @default.
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