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• W2058995004 endingPage "1218" @default.
• W2058995004 startingPage "1214" @default.
• W2058995004 abstract "Infrared spectroscopy has been used to probe the interaction between water and the hydrophobic solvent, carbon tetrachloride. At room temperature, water exists as monomers in carbon tetrachloride, presenting a system for studying the rotational properties of water free of strong hydrogen-bonding. The rotational structure suggests a very anisotropic motion consisting of essentially free rotation about the symmetry axis and highly hindered rotation about the two perpendicular axes of the asymmetric water molecule. The rotational lifetime is significantly shortened relative to gas-phase water. An upper limit of 0.93 ps is deduced from the spectrum. Interaction with carbon tetrachloride also slightly enhances the intensity of the symmetric stretch. The results are compared with results of interactions between water and the cations Li+, Na+, K+, and Cs+. It is concluded that the attractive interaction is between the oxygen of water and the electropositive carbon of carbon tetrachloride." @default.
• W2058995004 created "2016-06-24" @default.
• W2058995004 creator A5041567598 @default.
• W2058995004 creator A5050795574 @default.
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• W2058995004 date "2008-01-23" @default.
• W2058995004 modified "2023-10-18" @default.
• W2058995004 title "Rotational Structure of Water in a Hydrophobic Environment: Carbon Tetrachloride" @default.
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• W2058995004 doi "https://doi.org/10.1021/jp7097284" @default.
• W2058995004 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18211044" @default.
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