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• W2059017351 abstract "Abstract Chiral intermediates were prepared by biocatalytic processes for the chemical synthesis of four pharmaceutical drug candidates. These include: (i) the microbial reduction of 3,5‐dioxo‐6‐(benzyloxy) hexanoic ethyl ester to (3 S ,5 R )‐dihydroxy‐6‐(benzyloxy) hexanoic acid ethyl ester, an intermediate for a new anticholesterol drug; (ii) synthesis of (2 R ,3 S )‐(‐)‐ N ‐benzoyl‐3‐phenyl isoserine ethyl ester, a taxol side‐chain synthon; (iii) the microbial oxygenation of 2,2‐dimethyl‐2H‐1‐benzopyran‐6‐carbonitrile to the corresponding (3 S ,4 S ) epoxide and (3 S ,4 R )‐ trans diol, intermediates for synthesis of potassium channel opener; (iv) the biotransformation of (exo,exo)‐7‐oxabicyclo [2.2.1] heptane‐2,3‐dimethanol to the corresponding chiral lactol and lactone, intermediates for thromboxane A 2 antagonist." @default.
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• W2059017351 date "1995-11-01" @default.
• W2059017351 modified "2023-09-29" @default.
• W2059017351 title "Synthesis of four chiral pharmaceutical intermediates by biocatalysis" @default.
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• W2059017351 doi "https://doi.org/10.1007/bf02546196" @default.
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