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- W2059022472 abstract "Rotational isomers of seven peri-substituted 9-(1,1-dimethyl-2-phenylethyl)triptycene derivatives were stereoselectively synthesized and classical kinetics on rotational isomerization were studied. While compounds with relatively small peri-substituents (F and OCH3) showed higher barriers than the peri-unsubstituted one, the peri-chloro compound had almost the same barrier with and those carrying bulkier peri-substituents (Br, CH3, and CF3) showed lower barriers than the peri-unsubstituted one. These apparently anomalous phenomena may be explained in terms of large molecular deformation of these highly congested compounds." @default.
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- W2059022472 date "1983-01-01" @default.
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- W2059022472 title "Restricted Rotation Involving the Tetrahedral Carbon. XLV. Appearance of a Maximum in the Rotational Barriers of 9-(1,1-Dimethyl-2-phenylethyl)triptycenes at a Medium-sized<i>peri</i>-Substituent" @default.
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- W2059022472 doi "https://doi.org/10.1246/bcsj.56.306" @default.
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