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- W2059028619 abstract "Reaction of [RGa(μ3-Te)]4 (R = tBu, CMeEt2) and O2, SO2 or SeO2 yields, in addition to tellurium metal, [RGa(μ3-O)]n (R = tBu, n = 9; R = CMeEt2, n = 6) and the mixed cubanes [R4Ga4(μ3-O)x(μ3-Te)4 − x] (x = 1, 2); neither [R4Ga4(μ3-O)3(μ3-Te)] or [RGa(μ3-O)]4 are observed; DFT calculations show no global minimum for [Me4Ga4(μ3-Te)2(μ3-O)2] or [Me4Ga4(μ3-Te)2(μ3-O)2], suggesting that these structures would rearrange to more favored structures on the pathway to a final geometry lower in energy." @default.
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- W2059028619 date "2001-01-01" @default.
- W2059028619 modified "2023-10-18" @default.
- W2059028619 title "An investigation of the reaction of [RGa(µ3-Te)]4 with O2, SO2 and SeO2 using a combination of experiment and density functional theory" @default.
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- W2059028619 doi "https://doi.org/10.1039/b106998p" @default.
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