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• W2059032023 abstract "The efficient synthesis of enantiopure, trisubstituted cryptophane-A derivatives, organic host molecules with unusually high xenon affinity, is reported. Synthesis and chromatographic separation of (±) tri-Mosher’s acid substituted cryptophane diastereomers gave ready access to the enantiopure cryptophanes, which are critical components in the design of enantiomerically pure 129Xe biosensors. Hyperpolarized 129Xe NMR spectroscopy identified single resonances for both trisubstituted cryptophane diastereomers that were separated by 9.5 ppm. This highlights opportunities for using enantiopure xenon biosensors in the simultaneous detection of 129Xe in different biochemical environments." @default.
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• W2059032023 date "2012-07-11" @default.
• W2059032023 modified "2023-09-23" @default.
• W2059032023 title "Synthesis of Enantiopure, Trisubstituted Cryptophane-A Derivatives" @default.
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• W2059032023 doi "https://doi.org/10.1021/ol300943w" @default.
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