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• W2059092189 endingPage "671" @default.
• W2059092189 startingPage "667" @default.
• W2059092189 abstract "Ion transfer across the polarized interface between a room-temperature ionic liquid (RTIL) or room-temperature molten salt, tetrahexylammonium bis(trifluoromethylsulfonyl)imide (THAC(1)C(1)N), and water has been studied voltammetrically using a micro liquid-liquid interface formed at the orifice of a glass capillary micropipette. A small current of nanoampere level circumvents the problem of the iR drop in the viscous ionic liquid phase. Voltammograms for the transfer of moderately hydrophilic ions, such as BF(4)(-) and ClO(4)(-), from the aqueous phase in the capillary to the bulk of THAC(1)C(1)N in which the capillary is submerged, show steady-state characteristics in that the current does not depend on the scan rate up to a few hundred millivolt per second, and the plateau in the limiting current region is proportional to the bulk concentration of analyte ions. Owing to the steady-state current, which is presumably ascribed to a noncylindrical geometry of the capillary tip, the relative magnitude of the hydrophobicity, or the affnity to the RTIL, of a series of ions can be determined from the half-wave potentials of voltammograms." @default.
• W2059092189 created "2016-06-24" @default.
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• W2059092189 date "2006-05-01" @default.
• W2059092189 modified "2023-10-18" @default.
• W2059092189 title "Voltammetry of Ion Transfer across the Electrochemically Polarized Micro Liquid-Liquid Interface between Water and a Room-temperature Ionic Liquid, Tetrahexylammonium Bis(trifluoromethylsulfonyl)imide, Using a Glass Capillary Micropipette" @default.
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• W2059092189 doi "https://doi.org/10.2116/analsci.22.667" @default.
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