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- W2059093852 abstract "Hydrosilylation reaction of allyl acetate (AA) with octakis(dimethylsiloxy)octasilsesquioxane [(HSiMe2O)8(SiO1.5)8] was efficiently catalyzed by chloro(1,5-cyclooctadiene)iridium(I) dimer [Ir(μ-Cl)(COD)]2. The effects of the catalyst amounts and the reaction conditions on the conversion and the product selectivity were investigated. [Ir(μ-Cl)(COD)]2 catalyst was also applied to the hydrosilylation reaction of AA with other hydrosilanes such as pentamethyldisiloxane, 1,1,3,3-tetramethyldisiloxane, octahydridosilsesquioxane, triethoxysilane and tris(trimethylsiloxy)silane in order to compare their structure–reactivity relationship." @default.
- W2059093852 created "2016-06-24" @default.
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- W2059093852 date "2014-02-01" @default.
- W2059093852 modified "2023-10-11" @default.
- W2059093852 title "Ir-catalyzed hydrosilylation reaction of allyl acetate with octakis(dimethylsiloxy)octasilsesquioxane and related hydrosilanes" @default.
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- W2059093852 doi "https://doi.org/10.1016/j.jorganchem.2013.11.035" @default.
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