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- W2059097727 abstract "Ba-doped Y2O3 is one of the most active catalysts for the oxidative coupling of methane. Here, based on measurements of the oxygen K-edge X-ray absorption edge, X-ray diffraction, X-ray fluorescence, and X-ray photoelectron spectroscopy and its catalytic activity and selectivity, we propose that the active sites are charge-deficient oxygen sites created as Bat+ substitutes into Y3+ lattice sites. The substitution is temperature dependent, becoming significant only at higher temperatures. We have found a correlation of catalytic activity and selectivity as a function of Ba loading on Y203. This is reflected in the oxygen K-edge absorption near the absorption edge." @default.
- W2059097727 created "2016-06-24" @default.
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- W2059097727 date "1992-07-01" @default.
- W2059097727 modified "2023-09-26" @default.
- W2059097727 title "Oxygen X-ray absorption near-edge structure characterization of the Ba-doped yttria oxidative coupling catalyst" @default.
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- W2059097727 doi "https://doi.org/10.1016/0021-9517(92)90102-n" @default.
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