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• W2059169900 endingPage "2902" @default.
• W2059169900 startingPage "2893" @default.
• W2059169900 abstract "Abstract The efficient desymmetrization of 2,3‐bicyclic hydrazines with boronic acids through rhodium‐catalyzed ring‐opening or reductive arylation is described. Excellent levels of enantioselectivity are achieved in ring‐opening with ortho ‐substituted boronic acids, using Josiphos‐type ligands. Alternatively, reductive arylation occurs selectively with electron‐poor Josiphos and Walphos ligands. A CH activation/1,4‐migration mechanism was established through deuterium transfer experiments." @default.
• W2059169900 created "2016-06-24" @default.
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• W2059169900 date "2008-12-01" @default.
• W2059169900 modified "2023-10-17" @default.
• W2059169900 title "Ligand Control in Enantioselective Desymmetrization of Bicyclic Hydrazines: Rhodium(I)-Catalyzed Ring-Opening<i>versus</i>Hydroarylation" @default.
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• W2059169900 doi "https://doi.org/10.1002/adsc.200800587" @default.
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